The girl was just 13 when she was spotted by a modeling scout with her mother along the streets of Budapest. She shot her first editorial in 2006 for Spur Magazine, and subsequently moved to Asia where she remained with regular bookings. Palvin has appeared on pages of Vogue (Portugal), Marie Claire, (Italy), Glamour, (Hungary), Elle (Great Britain), Italy, Brazil, Argentina and Sweden), Elle (Great Britain), Elle (Portugal), Allure, GQ, Harper's Bazaar, (Australia, Greece), Singapore, South Korea), Jealouse Magazine, Numero (Netherlands), Russia. Palvin was featured in ads for Armani Exchange (H&M), Victoria's Secret and Pull & Bear. In February 2012, she was made an ambassador for L'Oreal Paris. In the year 2016, Palvin was revealed to be part of the Sports Illustrated Swimsuit Rookie Class. Palvin was also the new face for Armani's signature scent, "Acqua Di Gioia". Palvin is the face of Amazon Fashion and appeared on Express and Chaos advertising campaigns.Her runway debut was with Prada during Milan Fashion Week in February 2010. Palvin has appeared on runways for Louis Vuitton and Miu Miu and also Nina Ricci, Christopher Kane and Emanuel Ungaro. She also was a model in the runway of Prada's debut during Milan Fashion Week, which took place in February 2010. In 2012, she was a model in the Victoria's Secret Fashion Show.

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